Capture Master ! The Pirate Alliance's Operation Begins!

Zoro, Brook and Sanji are trying to find the samurai. Earlier they got knocked out by the Yeti Cool Brothers. Caesar's hazmat subordinates attack them but fail. They find the samurai's head frozen and unfroze him. They see Smiley far away. Smiley is a chemical experiment that caused the explosion in Punk Hazard. Law and Chopper are heading to the lab. Caesar drugged his test subjects to experiment on them. G-5 Marines attempt to break inside lab and then Luffy, Franky and Robin arrive out of nowhere surprising the Marines and Caesar's subordinates.

Destruction Crisis - The Monster of Death Flies in

Luffy declares that he will capture Caesar. Law says he will deal with Monet while Chopper tries to find an antidote. Luffy and his group try to find the entrance to lab. Tashigi and Smoker attack Luffy, with Smoker gaining an advantage until Luffy uses Gear Second and tells Smoker to fight him later when he is at full strength. Back in the lab, the children start to wake up until Usopp puts them to sleep again. They then see pieces of Smiley falling onto the stolen warship. Franky, not being able to find an entrance, uses his Radical Beam to make an opening. The Marines try attacking it but discover that it emits poison gas when they touch it. One of them tries to burn it but it explodes when it catches on fire, destroying the ship. Back in the burning lands, Zoro, Sanji, Brook and The Samurai see Smiley shooting pieces of itself across the lake. Caesar then appears on top of the lab, explaining that Smiley was his experiment and that it is weak against water which is why it is shooting itself across the lake. After his speach, Luffy jumps up and grabs him.

Big Battle ! Caesar Activates his True Ability!

Sanji, Kin'emon, Brook and Zoro see Smiley. Brook talks about a story about slime eating the clothes off of women making everyone act perverted except for Zoro, who points out that the slime is killing the fish in the lake, prompting Sanji to jump in to find Kin'emon's torso. Law tells Monet to take a walk with him while Chopper is left in the lab to find the antidote. Luffy faces off against Caesar who uses his Gas Robe attack until he discovers that Luffy is immune to poison. Caesar then uses his Gastanets and Smiley to injure Luffy who then grabs Caesar. Caesar then knocks Luffy out with an unknown ability. Robin, Franky, Tashigi and Smoker get knocked out as well. Law and Monet are walking down a hallway and encounter a mysterious figure who causes Law to break down in pain while the mysterious figure tells him that it's been a long time since they last met.

The Samurai that Cuts the Fire! Kin'emon of Foxfire

Law's heart is crushed by the mysterious man named Vergo who was sent along with Monet to watch over Caesar. Law gets knocked out by Vergo who had a bamboo stick with him imbued with Haki. Caesar tells his men to tie up the Straw Hats and G-5. Meanwhile Chopper is looking for a way to cure the children. Zoro's group are waiting for Sanji to rescue the samurai's torso. Sanji uses Haki to find the body and realizes it is in a shark's mouth. He manages to escape before the gas consumes him. The samurai then reveals himself as Kin'emon. He demonstrates his ability by cutting fire and by destroying the slime. He then attempts to find his son, Momonosuke. Zoro's group decides to aid him.

Shock! Identity of Vergo, the Mysterious Man

Vergo is still punishing Law and reveals that Vergo is the base commander of the G-5 Marine Base. On a unknown island inhabited by G-5 Marines that are extremely rude and take what they please. The citizens ask if they could look for their missing children. Revealing that the children in Ceaser Clown's laboratory were in fact kidnapped from this island. The Marines refused to help because they said Vergo looked over the missing reports and they all have died. Nami and Usopp who still are dealing with children who are going through severe withdrawals from not getting get any of their drug candy. Suddenly Caesar Clown appears and convinces the children to go back to the laboratory by bribing them with candy. Zorro's group are still dealing with Smiley and is furious that Kin'emon destroyed so much of the slime and decides to send huge slime attacks at them chasing them back to the laboratory. Luffy, Law, Robin, Franky, Tashigi, and Smoker in prison cell introduced to both Vergo and Monet. Meanwhile Caesar Clown's soldiers close all entrances to the laboratory leaving the G-5 Marines stranded outside to deal with Smiley. Vergo and Monet talk about what Caesar is planning but both are still quite not sure what he is planning. Smoker than calls out Vergo saying that his subordinates will die if he doesn't do anything. But, Vergo doesn't care less about what happens to them. Smoker pieces it together that Vergo is responsible for the cover-ups behind the missing children in the New World. Law then states that Vergo was never really loyal to the navy because he was originally a pirate all along working for the notorious underworld broker "Joker". Vergo then threatens both Tashigi and Smoker saying they will both die leaving his secret in tact. Luffy then asks Law "who is the Joker" and Law responds as someone that they all know who is a notorious pirate who works for the World Government. None other than, one of the Warlords Don Qiuxote Doflamingo.